Get the ADML and ADMX Group Policy files and deploy them in your environment.Windalready has OneDrive, so no deployment required.Otherwise if you’re starting fresh, there’s a great guide here to go through. If you’re migrating from an existing install, then you’ll need to follow this process. Since OneDrive is part of Windows 10 now, if you aren’t ready for this or don’t want it yet, you’ll need to use the Group Policy setting ‘Prevent the usage of OneDrive for file storage’ which is found in Computer Settings > Policies > Administrative Tempates > Windows Components > OneDrive (note that this is different to the location of where the above new policies sit for OneDrive, which is one level down straight under Administrative Templates). OneDrive.exe is the new client, where Groove.exe is the older. The newer client has much less syncing issues too – if you’re not sure what one you’re using, check what executable is running. There’s no deployment of the app required then, so you won’t need to use or modify OneDrive for Business.

You’ll need Windows 10 1709+ for this, as that’s the first version of Windows 10 that has OneDrive baked in. It’s just OneDrive now, even though the backend is OneDrive for Business as part of an Office 365 subscription. OneDrive for Business from the client’s perspective has been dropped. If you’re looking at starting to use OneDrive for Business and you’re working with a PCs joined to a local domain, you can now have a seamless sign in experience for end users (Note that the Group Policy setting for this is in preview according to the documentation).

Office 365 onedrive sync settings